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The atmosphere of Saturn's largest moon Titan is 98% Nitrogen with small amounts of Methane and Ethane mixed in. Earth's atmosphere is similar: 78% Nitrogen and 21% Oxygen. Earth and Titan are the only two bodies in the Solar System with substantial predominantly-Nitrogen atmospheres. Since Oxygen on Earth was all produced by lifeforms over billions of years, the atmosphere of early Earth was devoid of this gas just as Titan is today.